May 2022 | 66 pages, 9 tables, 18 figures | Download Table of contents
Metal-organic frameworks (MOFs) are self-assembled combinations of metals and inorganic ligands that result in a relatively young class of highly ordered, porous materials. MOFs with the ability to [selectively] adsorb molecules into their pores/ on their internal surfaces.
Due to their high surface area (>7000 m2/g), extremely high porosity and favourable thermal properties, MOFs are being investigated in gas storage and separation, purification, carbon capture, utilization and storage, electrochemical energy storage and sensing. Commercial activity has grown greatly in recent years. Baker Hughes has recently purchased Mosaic Materials, which makes carbon dioxide–capturing materials based on metal-organic frameworks (MOFs).
MOFs are highly attractive for a range of industrial applications as they use non-hazardous feedstock, are cost-effective and environmentally friendly. They are potentially key materials in industrial adsorption, storage processes and catalysis and are a leading technology candidate for carbon capture. MOFs can be used to store, separate, release or protect in a range of applications including:
- Air and water filtration.
- Carbon capture, utilization and storage.
- Gas storage and delivery, and natural gas storage and purification.
- Improved chemical separations.
- Batteries and supercapacitors.
- Food packaging.
- Anti-bacterials.
- Drug delivery.
- Fuel production.
- Solvent or heavy metal recovery.
- Adsorbents for organic pollutants.
- Water harvesting.
- Heat exchangers.
- Pharmaceuticals
A number of start-ups are bringing MOF products to the market, and production volumes have increased in the past two years.
Report contents include:
- Technical analysis of Metal-organic frameworks (MOFs).
- Applications of Metal-organic frameworks (MOFs).
- MOF industry developments 2021-2022
- Addressable markets for Metal-organic frameworks (MOFs). Markets covered include Coatings, Gas Capture, Separation and Storage, Biomedicine (Drug delivery, antibacterials, biosensors and bioimaging), Sensors, Air and Water Filtration, Water Harvesting, Batteries and Supercapacitors, Heat Exchangers and Air Conditioning.
- Estimated global market revenues to 2032, by market.
- Profiles of 22 companies including products and targeted markets. Companies profiled include Promethean Particles, MOF Technologies, Atomis, Water Harvesting, Inc., NuMat Technologies, novoMOF AG, MOFWORX.
1 INTRODUCTION 7
- 1.1 Properties 8
- 1.2 Materials 10
- 1.3 Synthesis 10
- 1.4 Applications 13
- 1.5 Industry developments 2021-2022 14
2 MARKETS FOR METAL-ORGANIC FRAMWEWORKS (MOF) 17
- 2.1 Coatings 17
- 2.1.1 Properties 17
- 2.1.2 Applications 17
- 2.2 Carbon Capture, Separation and Storage 18
- 2.2.1 Properties 18
- 2.2.2 Applications 18
- 2.3 Biomedicine 20
- 2.3.1 Drug delivery 20
- 2.3.2 Antibacterials 20
- 2.3.3 Biosensors and bioimaging 21
- 2.4 Sensors 22
- 2.4.1 Properties 22
- 2.4.2 Applications 22
- 2.5 Air and water filtration 24
- 2.5.1 Properties 24
- 2.5.2 Applications 24
- 2.6 Water harvesting 26
- 2.7 Batteries and supercapacitors 28
- 2.8 Heat exchangers 29
- 2.9 HVAC 30
3 GLOBAL MARKET REVENUES 2018-2032 31
4 MOF PATENTS 34
- 4.1 Global MOF patent applications 34
- 4.2 Patenting by sector 35
- 4.3 Patenting by regional authority 36
5 MOF PRODUCER PROFILES 37
6 EX-PRODUCERS 61
7 DISTRIBUTORS 63
8 REFERENCES 65
Tables
- Table 1. Summary of MOFs. 7
- Table 2. Properties and applications of metal-organic frameworks. 9
- Table 3. Example synthesis routes for MOFs. 11
- Table 4. Markets and applications of Metal-organic frameworks (MOFs). 13
- Table 5. MOF industry developments 2021-2022 14
- Table 6. Applications of MOFs in gas storage and separation. 18
- Table 7. MOF sensor applications. 22
- Table 8. Global market revenues for MOFs, 2018-2032, Millions USD. 31
- Table 9. Global market revenues for MOFs by market, 2018-2031, Millions USD. 32
Figures
- Figure 1. Schematic drawing of a metal–organic framework (MOF) structure.s 9
- Figure 2. MOF synthesis methods historically. 11
- Figure 3. Electrochemistry Synthesis method. 12
- Figure 4. Spray-drying method. 12
- Figure 5. Schematic of continuous flow microfluidic device for producing MOFs. 12
- Figure 6. NuMat’s ION-X cylinders. 18
- Figure 7. Antibacterial mechanisms of metal–organic frameworks. 21
- Figure 8. Capture mechanism for MOFs toward air pollutants. 24
- Figure 9. Schematic of a MOF-based device for water harvesting. 26
- Figure 10. MOF-coated heat exchanger. 29
- Figure 11. Global market revenues for MOFs, 2018-2031, Millions USD. 31
- Figure 12. Global market revenues for MOFs by market, 2018-2031, Millions USD. 33
- Figure 13. Global MOF patent applications 2001-2021. 34
- Figure 14. Patent applications by sector. 35
- Figure 15. Patent applications by authority. 36
- Figure 16. Mosaic Materials MOFs. 45
- Figure 17. MOF-based cartridge (purple) added to an existing air conditioner. 57
- Figure 18. Molecular sieving membrane. 58
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