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The Global Market for Self-Healing Materials, Polymers and Coatings to 2033

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Published December 2022 | 165 pages 44 tables, 55 figures | Download table of contents

The need for sustainable manufacturing solutions is driving the growing market interest in self-healing materials,  polymers and coatings.  The use of  self-healing materials, polymers and coatings can prolong the life of industrial materials, reducing plastic usage and negating the need to maintain and replace infrastructure.

Self-healing materials and coatings can heal or repair themselves automatically and autonomously from damage (e.g. mechanical or corrosion) without any external intervention. This process leads to the (partial) restoration of the original properties of these materials, in particular the mechanical properties.

Inspired by natural biological systems, continuous efforts are being made to mimic natural materials and integrate self-healing capabilities into coatings, polymers and polymer composites. Main types of self-healing systems are intrinsic and extrinsic. Intrinsic self-healing is chemically driven by noncovalent bonds or reversible chemical bonds. In extrinsic systems microcapsules or vascular networks release healing agents to damaged locations or wounds. The Global Market for Self-Healing Materials, Polymers and Coatings provides a comprehensive review of this technology area, players, and market. Report contents include:

  • Global revenues for self-healing materials, polymers and coatings-historical and forecast to 2033. 
  • Analysis of self-healing materials, polymers and coatings, by type. 
  • Commercialised products.
  • Technology roadmap. 
  • Patent analysis. 
  • Analysis of self-healing materials, polymers and coatings, by market.
  • Profiles of 35 companies,  including in-depth information on products and target markets. Companies profiled include A2O Advanced Materials Inc., ASM, Inc., Basilisk, CompPair Technologies Ltd., Helicoid Industries and Tandem Repeat.

 

 

1              EXECUTIVE SUMMARY   13

  • 1.1          Market opportunity for self-healing materials and coatings            13
  • 1.1          Commercialising self-healing products    16
    • 1.1.1      Construction materials   16
    • 1.1.2      Self-healing paint protection film              16
    • 1.1.3      PVC cutting mats              17
  • 1.2          Global market revenues, historical and forecast to 2033  18
    • 1.3.1      By market           19

 

2              RESEARCH METHODOLOGY         21

  • 2.1          Report scope     21
  • 2.2          Market opportunity analysis        21

 

3              INTRODUCTION 24

  • 3.1          Self-healing mechanism and categorization          24
    • 3.1.1      Extrinsic self-healing       27
    • 3.1.2      Capsule-based  27
    • 3.1.3      Vascular self-healing      27
    • 3.1.4      Intrinsic self-healing       28
    • 3.1.5      Healing volume 29
  • 3.2          Types of self-healing materials, polymers and coatings    30
    • 3.2.1      Self-healing coatings       31
    • 3.2.2      Anti-corrosion   32
    • 3.2.3      Scratch repair    32
    • 3.2.4      Self-healing polymers    32
      • 3.2.4.1   Thermally reversible reactions   34
      • 3.2.4.2   Photoreversible reactions            35
      • 3.2.4.3   Molecular interdiffusion               35
      • 3.2.4.4   Reversible bond formation          36
    • 3.2.5      Self-healing metals          38
    • 3.2.6      Self-healing fiber-reinforced polymer composites             39
    • 3.2.7      Metal matrix composites              39
    • 3.2.8      Self-Healing and Morphing Composites  40
    • 3.2.9      Self-healing ceramics and ceramic composites    41
    • 3.2.10    Self-healing nanomaterials          41
    • 3.2.11    Self-healing biomaterials              42
    • 3.2.12    3d printing of self-healing materials         42
    • 3.2.13    Factors affecting self-healing      43

 

4              SELF-HEALING MATERIALS, POLYMERS AND COATINGS ANALYSIS               45

  • 4.1          Polyurethane clear coats               45
    • 4.1.1      Properties           45
    • 4.1.2      Markets               45
  • 4.2          Micro-/nanocapsules     47
    • 4.2.1      Properties           47
    • 4.2.2      Markets               47
  • 4.3          Microvascular networks 48
    • 4.3.1      Properties           48
    • 4.3.2      Markets               48
  • 4.4          Reversible polymers       48
    • 4.4.1      Properties           48
    • 4.4.2      Markets               49
  • 4.5          Click polymerization       49
    • 4.5.1      Properties           49
    • 4.5.2      Markets               49
  • 4.6          Self-healing hydrogels   50
    • 4.6.1      Self-healing mechanisms              50
      • 4.6.1.1   Hydrogen Bonding           51
      • 4.6.1.2   Ionic Bonds         51
      • 4.6.1.3   Host-Guest Interactions 51
      • 4.6.1.4   Hydrophobic Bonds         51
      • 4.6.1.5   Imine Bonds       52
      • 4.6.1.6   Arylhydrazone bonds     52
      • 4.6.1.7   Diels-Alder Reaction       52
    • 4.6.2      Types and materials        53
      • 4.6.2.1   Natural Polymers             54
      • 4.6.2.2   Synthetic polymers         55
      • 4.6.2.3   Polyampholyte self-healing hydrogels     55
      • 4.6.2.4   Peptides              56
      • 4.6.2.5   Mussel-inspired proteins              56
      • 4.6.2.6   Bacterial cellulose            56
      • 4.6.2.7   Conductive polymers     57
      • 4.6.2.8   Zwitterionic polymers    59
      • 4.6.2.9   Nanomaterial self-healing hydrogels       59
    • 4.6.3      Markets and applications              61
  • 4.7          Carbon nanotubes           62
    • 4.7.1      Properties           62
  • 4.8          Graphene and other 2D materials             65
    • 4.8.1      Properties           65
  • 4.9          Shape memory-assisted self-healing        66
    • 4.9.1      Properties           66
  • 4.10        Self-healing proteins      68
    • 4.10.1    Properties           68
  • 4.11        Piezoelectric crystals       69

 

5              PATENT ANALYSIS            70

 

6              TECHNOLOGY READINESS LEVEL (TRL)     71

 

7              MARKETS FOR SELF-HEALING MATERIALS, POLYMERS AND COATINGS     75

  • 7.1          Aerospace          77
    • 7.1.1      Market drivers  77
    • 7.1.2      Applications       78
      • 7.1.2.1   Self-healing composites 78
      • 7.1.2.2   Self-healing thermal interface materials 79
    • 7.1.3      Commercial activity         79
    • 7.1.4      Market opportunity        79
    • 7.1.5      Revenues            80
  • 7.2          Automotive        82
    • 7.2.1      Market drivers  82
    • 7.2.2      Applications       82
      • 7.2.2.1   Self-healing glass              82
      • 7.2.2.2   Self-healing coatings for scratch repair    83
      • 7.2.2.3   Self-healing composites 83
      • 7.2.2.4   Self-healing tires              84
    • 7.2.3      Commercial activity         84
    • 7.2.4      Market opportunity        85
    • 7.2.5      Revenues            86
  • 7.3          Electronics          88
    • 7.3.1      Market drivers  88
    • 7.3.2      Applications       88
      • 7.3.2.1   Colorless polyimides (CPIs)          89
      • 7.3.2.2   Self-healing consumer electronic device coatings               89
      • 7.3.2.3   Flexile insulators               91
      • 7.3.2.4   Self-healing flexible and stretchable wearables   91
      • 7.3.2.5   Self-healing soft robotics              92
    • 7.3.3      Commercial activity         92
    • 7.3.4      Market opportunity        92
    • 7.3.5      Revenues            93
  • 7.4          Energy  95
    • 7.4.1      Applications       95
      • 7.4.1.1   Self-healing materials for Lithium batteries           95
      • 7.4.1.2   Self-healing flexible batteries     96
      • 7.4.1.3   Fuel cells              96
      • 7.4.1.4   Gas turbine coatings       97
      • 7.4.1.5   Wind energy      97
      • 7.4.1.6   Solar panels        97
    • 7.4.2      Commercial activity         98
    • 7.4.3      Market opportunity        99
    • 7.4.4      Revenues            100
  • 7.5          Elastomers          101
    • 7.5.1      Market drivers  101
    • 7.5.2      Applications       101
      • 7.5.2.1   Self-healing elastomers 101
    • 7.5.3      Commercial activity         103
    • 7.5.4      Market opportunity        103
    • 7.5.5      Revenues            104
  • 7.6          Construction      105
    • 7.6.1      Market drivers  105
    • 7.6.2      Applications       106
      • 7.6.2.1   Self-healing concrete     106
      • 7.6.2.2   Fibre concrete   108
      • 7.6.2.3   Self-healing road surfaces and asphalt    108
      • 7.6.2.4   Self-Healing structural ceramics 108
    • 7.6.3      Commercial activity         109
    • 7.6.4      Market opportunity        109
    • 7.6.5      Revenues            110
  • 7.7          Paint and coatings           112
    • 7.7.1      Market drivers  112
    • 7.7.2      Applications       112
      • 7.7.2.1   Self-healing anti-corrosion and anti-fouling surfaces         112
      • 7.7.2.2   Self-healing polymer film and paint          113
    • 7.7.3      Commercial activity         113
    • 7.7.4      Market opportunity        114
    • 7.7.5      Revenues            114
  • 7.8          Healthcare          116
    • 7.8.1      Market drivers  116
    • 7.8.2      Applications       116
      • 7.8.2.1   Self-healing hydrogels   117
      • 7.8.2.2   Self-healing dental composites  119
      • 7.8.2.3   Self-healing orthopaedic implants             119
      • 7.8.2.4   Self-healing electronic skin           119
      • 7.8.2.5   Strain biosensors             120
    • 7.8.3      Commercial activity         120
    • 7.8.4      Market opportunity        120
    • 7.8.5      Revenues            121
  • 7.9          Other markets   123
    • 7.9.1      Filtration              123
      • 7.9.1.1   Applications       123
    • 7.9.2      Textiles 124
      • 7.9.2.1   Applications       124
    • 7.9.3      Military 126
      • 7.9.3.1   Applications       126
    • 7.9.4      Oil and gas          126
      • 7.9.4.1   Applications       127
    • 7.9.5      Marine 128
      • 7.9.5.1   Applications       128
      • 7.9.5.2   Commercial activity         129

 

8              COMPANY PROFILES       132 (35 company profiles)

 

9              REFERENCES       154

 

List of Tables

  • Table 1. The market for self-healing materials, polymers and coatings to 2015-2033, Millions USD, total, conservative and high estimates.        18
  • Table 2. Types of self-healing coatings and materials.       30
  • Table 3. Comparative properties of self-healing materials.             31
  • Table 4. Healing mechanism for different materials.         31
  • Table 5. Properties of self-healing polymers.        36
  • Table 6. Recent research in self-healing metals.  38
  • Table 7. Types of self-healing nanomaterials.       42
  • Table 8. Influencing factors and their effects on healing efficiency.            43
  • Table 9. Companies producing polyurethane clear coat products for self-healing. 45
  • Table 10. Self-healing natural polymers. 54
  • Table 11. Synthetic polymers.     55
  • Table 12. Components, preparation and properties of representative conductive polymer hydrogels.        58
  • Table 13. Properties of graphene.             59
  • Table 14. Applications of self-healing hydrogels. 61
  • Table 15. Properties of graphene.             65
  • Table 16. Technology Readiness Level (TRL) Examples.    72
  • Table 17. Self-healing materials and coatings markets and applications.   76
  • Table 18. Market drivers for self-healing materials in aerospace. 77
  • Table 19. Commercial activity in self-healing aerospace applications.        79
  • Table 20. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the aerospace sector, conservative and high estimates. 80
  • Table 21. Market drivers for self-healing materials in the automotive sector.         82
  • Table 22. Commercial activity in self-healing automotive applications.     84
  • Table 23. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the automotive sector, conservative and high estimates. 86
  • Table 24. Market drivers for self-healing materials in electronics.               88
  • Table 25. Commercial activity in self-healing energy applications.               92
  • Table 26. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the electronics sector, conservative and high estimates. 94
  • Table 27. Commercial activity in self-healing energy applications.               98
  • Table 28. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the energy sector, conservative and high estimates.              100
  • Table 29. Market drivers for self-healing materials in elastomers.               101
  • Table 30. Types of self-healing elastomers.           101
  • Table 31. Commercial activity in self-healing elastomers. 103
  • Table 32. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the elastomers sector, conservative and high estimates. 105
  • Table 33. Market drivers for self-healing materials in construction.            105
  • Table 34. Types of self-healing concrete.               107
  • Table 35. Commercial activity in self-healing construction applications.    109
  • Table 36. The market for self-healing materials, polymers and coatings 2015-2033,, Millions USD, in the construction sector, conservative and high estimates. 111
  • Table 37. Market drivers for self-healing materials in paint and coatings. 112
  • Table 38. Commercial activity in self-healing paints and coatings applications.      113
  • Table 39. The market for self-healing materials and polymers in paints and coatings 2015-2033, Millions USD, in the construction sector, conservative and high estimates.     115
  • Table 40. Market drivers for self-healing materials in healthcare. 116
  • Table 41. Commercial activity in self-healing healthcare applications.       120
  • Table 42. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the healthcare sector, conservative and high estimates. 122
  • Table 43. Market drivers for self-healing materials in the oil and gas.        126
  • Table 44. Commercial activity in self-healing marine applications.               129

 

List of Figures

  • Figure 1. Opportunity analysis matrix for self-healing coatings and materials.        13
  • Figure 2. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, total, conservative and high estimates.        18
  • Figure 3. The global market for self-healing materials, polymers and coatings 2015-2033, Millions USD, by market, conservative estimate.  19
  • Figure 4. The global market for self-healing materials, polymers and coatings 2015-2033, Millions USD, by market, high estimate.             20
  • Figure 5. Self-healing mechanism found in nature.            24
  • Figure 6. Schematic of self-healing polymers. Capsule based (a), vascular (b), and intrinsic (c) schemes for self-healing materials.  Red and blue colours indicate chemical species which react (purple) to heal damage.  26
  • Figure 7. Stages of self-healing mechanism.         26
  • Figure 8. Self-healing mechanism in vascular self-healing systems.             27
  • Figure 9. Comparison of self-healing systems.     28
  • Figure 10. Self-healing mechanism of polymers. 33
  • Figure 11. Applications of self-healing elastomers.            38
  • Figure 12. Illustration of BN precipitation on the creep cavity surface in stainless steel.     38
  • Figure 13. Schematic diagram of influencing factors on self-healing efficiency.     43
  • Figure 14. Schematic of the self-healing concept using microcapsules with a healing agent inside.                47
  • Figure 15. Healing process in a hydrogel.               51
  • Figure 16. Chemical and noncovalent interactions behind self-healable hydrogels.             53
  • Figure 17. (A) Wound self-healing process (B) Different forms of wound dressings.             57
  • Figure 18. Schematic of single-walled carbon nanotube. 64
  • Figure 19. Self-healing materials patent analysis 2010-2022.          70
  • Figure 20. TRL for self-healing materials, polymers and coatings. 73
  • Figure 21. Microspheres incorporating self-healing materials.      75
  • Figure 22. Flow of self-healing materials into the crack site.           76
  • Figure 23. Opportunity analysis matrix for self-healing materials, polymers and coatings in the aerospace sector. 80
  • Figure 24. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the aerospace sector, conservative and high estimates. 80
  • Figure 25. Nissan Scratch Shield.                83
  • Figure 26. Lamborghini self-healing sports-car.   84
  • Figure 27. Self-healing tires.        84
  • Figure 28. Opportunity analysis matrix for self-healing materials, polymers and coatings in the automotive sector.                85
  • Figure 29. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the automotive sector, conservative and high estimates. 86
  • Figure 30. Self-healing dielectric material for wearable electronics.            89
  • Figure 31. Self-healing patent schematic.              90
  • Figure 32. Self-healing coating on glass.  90
  • Figure 33. Self-healing glass developed at the University of Tokyo.             91
  • Figure 34. Opportunity analysis matrix for self-healing materials, polymers and coatings in electronics.     93
  • Figure 35. The market for self-healing materials, polymers and coatings 2015-2033,, Millions USD, in the electronics sector, conservative and high estimates. 94
  • Figure 36. Schematic of self-healing solar cell.      98
  • Figure 37. Opportunity analysis matrix for self-healing materials, polymers and coatings in energy.             99
  • Figure 38. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the energy sector, conservative and high estimates.              100
  • Figure 39. Self-healing rubber.   102
  • Figure 40. SeRM elastomers.      102
  • Figure 41. Opportunity analysis matrix for self-healing materials, polymers and coatings in elastomers.    103
  • Figure 42. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the elastomers sector, conservative and high estimates. 104
  • Figure 43. Self-healing bacteria crack filler for concrete. 107
  • Figure 44. Self-healing concrete.               107
  • Figure 45. Opportunity analysis matrix for self-healing materials, polymers and coatings in construction.  110
  • Figure 46. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the construction sector, conservative and high estimates. 111
  • Figure 47. Opportunity analysis matrix for self-healing materials, polymers in paints and coatings.               114
  • Figure 48. The market for self-healing materials and polymers in paints and coatings 2015-2033, Millions USD, in the construction sector, conservative and high estimates.     115
  • Figure 49. Opportunity analysis matrix for self-healing materials, polymers and coatings in healthcare.     121
  • Figure 50. The market for self-healing materials, polymers and coatings 2015-2033, Millions USD, in the healthcare sector, conservative and high estimates. 122
  • Figure 51. Self-healing fabrics.    125
  • Figure 52. Schematic of the nanocapsule-based self-healing coatings.       129
  • Figure 53. Sensicrete compound.              139
  • Figure 54.CompPair self-healing prepregs.            141
  • Figure 55. Tandem Repeat Self-Healing Squitex Fiber.      152

 

 

  

The Global Market for Self-Healing Materials, Polymers and Coatings to 2033
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